Publications Scientifiques
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Item Influencing parameters on the electrodeposition of silver from the effluents of mirror industry(Sociedade Portuguesa de Electroquimica, 2022) Bounechache, Foudil; Ghemmit-Doulache, N.; Bourouis, D.Silver (Ag) is considered as an ancient and durable precious metal that is used in different ways, due to its specific properties. The diversity of its uses has been meeting a growing worldwide demand that exceeds the Ag amount extracted from earth crust (primary resource), where a large part of this metal has been exploited. Due to its toxicity, environmental pollution resulting from industrial plants, and high economic value, Ag recovery from industrial plants (second resource) has become increasingly important for scientists. In this study, we focused on Ag recovery from the effluents of mirror industry. This was done by Ag electrodeposition on an aluminum (Al) electrode surface. This work aimed to study the effect of current intensity (CI), electrolysis time (ET), voltage (V) and temperature (T) parameters on Ag electrodeposition, in order to optimize them. According to the obtained results, the optimal parameters were a CI of 4 A, during an ET of 30 min, at 12.5 V, with a maximum T of 30 ºC. Scanning electron microscope (SEM) analyses showed a multilayer rich Ag deposit on the Al surface, followed by a cluster of flowers of different sizes originated from reduced Ag0Item Study of scale inhibitor SI-4497 effect on calcareous deposit(Desalination Publications, 2021) Ghemmit-Doulache, Naima; Bourouis, Douniazed; Bounechache, FoudilCalcareous deposits in water desalination generate serious problems and lead to considerable economic losses. The aim of this study is to investigate the inhibition of calcareous deposits using polyphosphonate (scale inhibitor SI-4497), which is an ideal additive for desalination operations. We studied the recovery rate of titanium electrode, in the presence and absence of this inhibitor, using chronoamperometry. A cathodic potential of –1.3 V/SCE (SCE – saturated calomel electrode) is used at 1,000 rpm and at 20°C, 40°C, 60°C, 80°C. Levich’s law is verified before and after 1 h of electrodeposition in presence of an inhibitor. It was found that electrode recovery decreases with the addition of 3.5 ppm polyphosphonate (scale inhibitor SI-4497), resulting in an efficiency of 63.65%
