Publications Scientifiques
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Item Catalytic effects of eggshell ash on the conversion of used engine oil to fuel by pyrolysis(Taylor and Francis, 2022) Zerdane, Youghourta; Largeau, Jean François; Hachemi, Madjid; Tazerout, MohandThe objective of this work is to recycle used engine oil until it is converted into an alterna- tive fuel by catalytic pyrolysis. The effect of using eggshell ash as a catalyst in pyrolysis reac- tions on the yield of the resulting fractions was investigated. In addition, the influence of this catalyst on the compositions and the quality of the non-condensable gas and liquid fractions were analyzed. The results show that the liquid fraction recovered 97.02%wt; with 20%wt of the catalyst is predominant. The detection of aromatics 15.84%wt, olefins 32.74%wt, naphthenic 2.82%wt, paraffins 29.00%wt, and alcohols 20.50%wt, in the pyrolytic liquid and the observation of H2 15.22%wt, CH4 16.65%wt and other elements such as C4H8 21.93%wt in non-condensable gases, make it possible to predict the good usability of these products obtained as an alternative fuel.Item Experimental investigation on petroleum sludge valorization into fuel via pyrolysis process(Springer Science and Business Media B.V., 2017) Bellahcene, Amal; Hachemi, Madjid; Largeau, Jean-François; Tarabet, Lyes; Burnens, Gaëtan; Khiari, Karim; Tazerout, MohandOil sludge (OS) has been of key concern due to its continuing effect on the environment degradation. The huge quantities thrown yearly of this waste contain a high proportion of hydrocarbons which are valuable for recovery. This study focused on the oil sludge conversion into a fuel for a diesel engine by thermal/catalytic pyrolysis process. The experiments were conducted at atmospheric pressure in a batch reactor operated without and with two catalyst types: TiO2 (3 and 5 wt%) and Al2O3(3 and 5 wt%). Overall all test conditions followed in the OS pyrolysis, a considerable liquid fraction is recovered (around 70%), as compared to the gaseous fraction (around 25%) and the solid residue (around 5%). The characterization of the pyrolytic oil samples, containing approximately 11.70% of oxygen, showed also that the use of 5% of Al2O3 catalyst in the OS cracking provide the best fuel quality with a minimum viscosity value (3.5 mm2/s), a maximum heating value (45.72 MJ/kg) with a hydrocarbon compounds in the range (C7–C32) which are detailed by GC–MS analysis. The others properties (density, flash point, pour point and cloud point) are found to be close to those of diesel fuel. Also, the catalysts effect is studied on the others pyrolysis products. The obtained results allow to predict the good usability as a diesel like fuel. Further tests to control engine performance and pollutant emissions could be done Graphic AbstractItem One-step synthesis and characterization of carbon nanospheres via natural gas condensate pyrolysis(Taylor and Francis, 2020) Boufades, Djamila; Hammadou Née Mesdour, Souad; Moussiden, Anissa; Benmebrouka, Hafsa; Hérold, Claire; Kaddour, OmarIn the current work, carbon nanospheres (CNSs) were prepared via pyrolysis of gas condensate in N2 at 1273 K and atmospheric pressure for 2 h using ferric chloride as a catalyst precursor. X-ray diffraction, energy dispersive X-ray spectrometry (EDX) in scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectrometry (Raman), Fourier transform infrared spectroscopy, and thermal gravimetric analysis (TGA) are employed for the structural and morphological characterization of the nanomaterials formed. The conductivity of these films was measured using the four probe method. As results, SEM-EDX and TEM analysis reveal spherical shaped particles, with diameter varying between 100 and 200 nm and graphene interlayer distance of 0.339 nm. The very low ID/IG ratio obtained reveals a relatively low amount of disorder in the nanostructures and TGA analysis implies that thermal stability was achieved after 470 °C. Our work provides a simple synthetic strategy in one-step sample preparation of CNSs, which can be used for furfur applications such as high-performance supercapacitors or adsorbentsItem Potential production of olefins in pyrolysis of Algerian gas condensate compounded with ethane(Springer, 2019) Bouarar, Fahima; Kaddour, Omar; Mimoun, Hadj; Khettab, NadjiaItem Truck tire pyrolysis optimization using the self-produced carbon black as a catalyst(2017) Akkouche, N.; Balistrou, Mourad; Hachemi, M.; Himrane, N.; Loubar, K.; Tazerout, M.Item Preparation of microporous activated carbon from date stones by chemical activation using zinc chloride(Taylor & Francis, 2017) Cherik, Dalila; Louhab, KrimItem Kinetic pyrolysis study and classification of date palm biomass(AIP Publishing, 2017) Bousdira, Khalida; Bousdira, Dina; Bekkouche, Sidi Mohamed El Amine; Nouri, L'Hadi; Legrand, JackItem Carbone nanospheres synthesis by pyrolysis of crude oil and optimization of parameters growth by response surface methodology (RSM)(Applied Chemistry, 2015) Boufades, Djamila; Pemanos Yelda, Bakoz; Mousidene, Anissa; Benmebrouka, Hafsa; Doumandji, Lotfi; Hamada, BoudjemaAlgerian oil as a new source of carbon is used to prepare the carbon nanospheres (CNSs) by pyrolysis method. A mixture of crude oil and FeCl3.6H2O solution as catalyst was injected into the reaction furnace to produce CNSs in an inert atmosphere, followed by multi step purification to remove different impurities. The carbon nanospheres have been characterized by scanning electron microscopy (SEM), energy dispersive X-rays spectroscopy (EDAX), X-ray diffraction(XRD), Raman spectroscopy and FTIRspectrum. The SEM image reveals that these CNSs have smooth surfaces and uniform particles with a diameter lower than 500 nm. the XRD and Raman studies shows that the graphitization degree of CNSs is not high , while the EDAX analysis shows that more than 98 % of the CNSs is carbon, FTIR proved the presence of new functions after samples treatment such as acid function. This study reports the optimization of various process parameters such as, temperature of reaction (860-940°C), process Time (90-150min)and mass ratio catalyst/Crude oil (0.83 10-3-2.4810-3 g/g) for increasing the Yield of CNSs. A MODDE 6.0 experimental design was employed for the optimization of synthesis of crude oil to ensure high production of carbon nanospheres in a low catalyst concentration and high temperature for a short length of time. The analysis of variance showed a high coefficient of determination value (R2 = 0.965) and Maximum CNSs production was predicted and experimentally validated, the optimized process conditions were identified to be reaction temperature of 900°C, duration synthesis of 113min and mass ratio catalyst /crude oil of 0.8 10-3 g/g with a yield of 13.23%