Publications Nationales
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Item Study of the adsorption of methylene blue by natural materials (olive stone, date pit and their mixture) in fixed bed column(ALJEST, 2019) Abed, Fatma; Aksa, H.; Abai, N.; Babakhouya, N.The present study focuses on the recovery of two agro-food waste available in our country with significant quantities olive pomace and date pits for the removal of a synthetic dye which is methylene blue. Both materials were used in their native forms separated and mixed to improve their adsorptive capacity. A range of physico-chemical analysis was performed to characterize adsorbents used, among them: the FTIR spectroscopy and the scanning electron microscopy. The ability of adsorbents prepared to adsorbe methylene blue (MB) from the aqueous solution was investigated in a fixed bed column. The effects of several important parameters were studied, such as initial concentration of MB, flow rate and bed height. The corresponding breakthrough curves were calculated.Item Activation et caractérisation d‘une zéolithe HY utilisée en qualité d’adsorbant(Aljest, 2018) Cherifi-Naci, HalimaL’article traite la préparation des matériaux zéolithiques activés dotés d’un pouvoir adsorbant très important dans le domaine de l’environnement. Nous avons procédé à la caractérisation physico-chimique et à la détermination des conditions optimales d’Activation (Concentration : 5M à la température T=90°C, Temps d’activation= 4h, Quantité d’H2SO4 adsorbée=1,75meq/g d’argile, Capacité d’échange cationique : CEC=70meq/100g d’argile, Surface spécifique=950 m2/g) en vue d’obtenir des zéolithes HY activées très performantes utilisées en qualité d’adsorbants. Les zéolithes HY activées ont été caractérisées par les techniques suivantes : Fluorescence X (pourcentage atomique), Diffraction des rayons X, le Microscope électronique à balayage et par des analyses physico-chimiques (Capacité d’échange cationique, la masse volumique, l’indice d’acidité, la surface spécifique et le diamètre moyen des pores).D’après les résultats des diffractogrammes RX , les zéolithes HY activées ne subissent aucunes modifications chimiques ni la destruction de leur réseaux cristallins et la création d’une structure cristalline plus uniforme .Les diamètres moyen des pores des zéolithes activées : Zéolithe HY à5M/70°C,Zéolithe HY à5M/90°C,Zéolithe HY à7M/70°C sont de l’ordre de 14,74 ; 15,02 et 17,01 A°, respectivement et leurs surfaces spécifiques sont de l’ordre de 650 ; 950 et 995 m2/g, respectivement. Les propriétés physiques des matériaux zéolithiques étudiés montrent une augmentation de la surface spécifique, la masse volumique et la porosité (diamètre moyen des pores) après traitement de la zéolithe HY par différentes concentrations à l’acide sulfurique, ces résultats confirment l’amélioration de la structure microporeuse et la création d’un réseau de tamis moléculaire plus développé. Avec les propriétés structurales et texturales déterminées, on peut conclure que les zéolithes activées ainsi obtenues sont des matériaux très réactifs et peuvent être utilisés dans des processus de dépollution des eaux usées industriellesItem Valorization of algerian leguminous: extraction and characterization of galactomannans(Aljest, 2018) Bouhadi, N.; Hachemi, N.; Kahlouche, A.; Djeziri, M.; Touabia, M.; Nouani, A.This study has an environmental objective based on the valorization of the seeds of legumes in order to obtain a clean nature, its seeds are considered as a good source of galactomannans which can replace other synthetic polysaccharides.They consists on the evaluation of physicochemical properties of galactomanans isolated from different seeds parts of two leguminous species widely known in Algeria: Gleditsia triacanthos and Ceratonia siliqua (carob), which represent an important source of polyscharids. The extraction gave an appreciable yield assessed at 12.97% of Gleditsia triacanthos and 11.45% of Ceratonia siliqua; values witch encourage their valorization. The physicochemical composition of the extracted galactomanans showed comparable characteristics in term of humidity; pH; °Brix and ashes. While; rheologic properties revealed that galactomanans solutions have a pseudo plastic nature. In the other hand; the functional properties analysis showed that the galactomanans obtained are soluble in water; the water absorption capacity was higher for Gleditsia triacanthos than Ceratonia siliqua with 20.62 and 5.98 respectively. Infrared analysis demonstrate that the same chemical structures of galactomanans were extracted from the two spices. NMR analysis allowed us to estimate the galactose / mannose ratio of the two extracts. This ratiois 1.25/1 and 3.63/1 of Gleditsia triacanthos and Ceratonia siliqua respectivelyItem Study of the adsorption of methylene blue by natural materials (olive stone, date pit and their mixture) in fixed bed column(Aljest, 2019) Abed, F.; Louhab, K.; Abai, Nadjet; Babakhouya, N.The present study focuses on the recovery of two agro-food waste available in our country with significant quantities olive pomace and date pits for the removal of a synthetic dye which is methylene blue. Both materials were used in their native forms separated and mixed to improve their adsorptive capacity. A range of physico-chemical analysis was performed to characterize adsorbents used, among them: the FTIR spectroscopy and the scanning electron microscopy. The ability of adsorbents prepared to adsorbe methylene blue (MB) from the aqueous solution was investigated in a fixed bed column. The effects of several important parameters were studied, such as initial concentration of MB, flow rate and bed height. The corresponding breakthrough curves were calculatedItem Adsorption of copper (ii) from aqueous solutions on antimony pillar/clay composite(Aljest, 2015) Cherifi, H .; Bougherara, S.; Louhab, K.The separation of copper from aqueous systems is studied for environmental protection. In this paper was studied the elimination of cooper from dilute aqueous solution by adsorption on a crude and chemical modified clays (pillared layers clays).The kinetics study of the adsorption of copper on the modified clay showed that equilibrium is reached after 60 mn. A high adsorption performance was recorded for the following optimum conditions at the temperature T = 25°C and the solid/liquid ratio = 2, Initial concentration of ion Cu2+ =40 mg /L, the amount of adsorbent clay = 800 mg, pH = 6Item Synthesis and Characterization of Algeria Organo clays used for Elimination of Phosphate Anions from Aqueous Solution(Aljest, 2020) Bandou, S.; Amrani, M.; Bouras, O.This study is based on synthesis and characterization of three different clays (Sodic-bentonite noted 𝑁𝑎−𝐵𝑡 , Dialyl Dimethyl Ammonium Chloride-bentonite noted 𝐷𝐷𝑀𝐴−𝐵𝑡 and bentonite intercalated by Hexadecyl Trimethyl Ammonium Bromide or 𝐻𝐷𝑇𝑀𝐴−𝐵𝑡 .These three clay complexes were characterized by both 𝑋𝑟𝑎𝑦 diffraction (𝑋𝑅𝐷) and Fluorescence (𝑋𝑅𝐹)Scanning Electron Microscopy (𝑆𝐸𝑀), Fourier transform infrared spectroscopy (𝐹𝑇𝐼𝑅),textural measurements (𝐵𝐸𝑇 specific surface areas and porosities) and the cationic exchange capacity (𝐶𝐸𝐶). Corresponding obtained results confirm the good intercalation of the 𝑁𝑎−𝐵𝑡 by the two used surfactants at low concentrations ( 0.006𝑀 for 𝐻𝐷𝑇𝑀𝐴𝐵 and 0.007𝑀for 𝐷𝐷𝑀𝐴+). Obtained results give basal spacing values around 14.5 and 18.5𝐴 , respectively for verified two aims firstly: The originality of this research, secondly for minimized the production cost of the adsorbents. Adsorption kinetic study of phosphate ions (𝑃𝑂43−) on these three matrices was carried out using kinetic models of pseudo-first, pseudo-second-order and intraparticular diffusion. Results obtained at the studied conditions (room temperature 𝑇=25𝑜𝐶 ), ( acidic medium 𝑝𝐻=5.7) show clearly the good validity of the pseudo-second-order model which gives a better correlation coefficient both, for 𝐷𝐷𝑀𝐴−𝐵𝑡 (𝑅2=0.995) and 𝐻𝐷𝑇𝑀𝐴−𝐵𝑡 (𝑅2=0.999) compared to that obtained by 𝑁𝑎−𝐵𝑡 (𝑅2=0.990)The aim of this present study was to evaluate the feasibility of using chicken eggshells as low-cost biosorbentfor nickel(II) ions adsorption from aqueous solutions. In order to clarify the adsorption process, batch experiments were performed to study the effect of operating parameters such asbiosorbent dose (1-10 g/L), initial concentration of nickel ions (10-50 mg/L), contact time (5-120 min) and temperature (20-50 °C). To describe the adsorption equilibrium, the experimental data were analyzed by the Langmuir, Freundlich and Temkin isotherm models. The Freundlich model showed better representation of data (R2> 0.999).The maximum adsorption capacity Adsorption isotherms give adsorbed amounts of about 33 and 63 𝑚𝑔.𝑔−1 onto 𝐷𝐷𝑀𝐴−𝐵𝑡 𝐻𝐷𝐷𝑀𝐴−𝐵𝑡 complexes, respectively, and 14 𝑚𝑔.𝑔−1for 𝑁𝑎−𝐵𝑡 as reference adsorbent. These results indicated the adsorption of phosphate anions (𝑃𝑂43−) by the twoItem A comparative study of raw and treated peach stones for the adsorption of hexavalent chromium: characterization, kinetic and thermodynamic modelling(2018) Khemmari, Fariza; Benrachedi, K.In the last years, much attention has been focused on the use of low-cost adsorbents for the removal of heavy metals from wastewater. The present study consists of comparing the adsorption of hexavalent chromium in aqueous solutions by two adsorbents: raw peach stones (RPS) and peach stones activated carbon (PSAC). The characterization of the adsorbents was done by using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Comparative study was carried out using adsorption parameters such as contact time, adsorbent dose and solution pH in a batch system. Results show that pH is key parameter for adsorption optimization. The time necessary to attain adsorption equilibrium was found 120 min for PSAC in the pH range 2-5.6 and 240 min for RPS at pH 2 with maximum removal percentage greater than 97% for both adsorbents. The adsorption process followed the pseudo-second order kinetics. Thermodynamic parameters revealed the spontaneous and endothermic nature of the adsorption process for both adsorbents. Investigations carried out proved that RPS and PSAC are good potential adsorbents for the treatment of toxic hexavalent chromium