Publications Scientifiques
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Item Etude potentielle de mélange des adsorbants naturels (grignons d’olive et noyaux de dattes) pour l’adsorption du chrome(Aljest, 2016) Aksas, Hammouche; Cherifi-Nacy, H.; Babaci, N.; Louhab, K.Cette étude a pour objectif d’étudier le potentiel d’utilisation de matériaux naturels (mélange homogène de noyaux de dattes et de grignons d’olives) issus de l’activité d’agriculture pour le traitement des eaux usées, chargées en polluant métallique: le chrome. Ces deux matériaux ont été activés chimiquement par l’acide phosphorique, en les mélangeant à différents pourcentages, afin d’obtenir une solution solide homogène et d’améliorer leur capacité adsorptive. L’adsorption des ions du chrome est étudiée en milieu dispersé (batch) à la fois sur les matériaux pur et à l’état du mélange à différentes proportions, composées d’une quantité fixe en noyaux de dattes (ND), et des quantités du grignon d’olive (GO) variées. Les résultats d’adsorption du chrome montrent : qu’elle est maximale à un pH =5.6, croit avec la température et avec la concentration initiale du chrome dans la solution. Le modèle de Langmuir stimule mieux les isothermes d’adsorption du chrome que d’autres modèles étudiés (avec un coefficient de corrélation de 0.9988 pour (88% NDI, 12% GOI). L’adsorption du chrome augmente avec l’augmentation du taux du grignon d’olive dans le mélange d’adsorbant (grignon d’olive et noyau de date).Item Study of the adsorption of methylene blue by natural materials (olive stone, date pit and their mixture) in fixed bed column(Aljest, 2019) Abed, F.; Louhab, K.; Abai, Nadjet; Babakhouya, N.The present study focuses on the recovery of two agro-food waste available in our country with significant quantities olive pomace and date pits for the removal of a synthetic dye which is methylene blue. Both materials were used in their native forms separated and mixed to improve their adsorptive capacity. A range of physico-chemical analysis was performed to characterize adsorbents used, among them: the FTIR spectroscopy and the scanning electron microscopy. The ability of adsorbents prepared to adsorbe methylene blue (MB) from the aqueous solution was investigated in a fixed bed column. The effects of several important parameters were studied, such as initial concentration of MB, flow rate and bed height. The corresponding breakthrough curves were calculatedItem Adsorption of copper (ii) from aqueous solutions on antimony pillar/clay composite(Aljest, 2015) Cherifi, H .; Bougherara, S.; Louhab, K.The separation of copper from aqueous systems is studied for environmental protection. In this paper was studied the elimination of cooper from dilute aqueous solution by adsorption on a crude and chemical modified clays (pillared layers clays).The kinetics study of the adsorption of copper on the modified clay showed that equilibrium is reached after 60 mn. A high adsorption performance was recorded for the following optimum conditions at the temperature T = 25°C and the solid/liquid ratio = 2, Initial concentration of ion Cu2+ =40 mg /L, the amount of adsorbent clay = 800 mg, pH = 6Item Étude de l’adsorption d’un colorant cationique en milieu aqueux sur le charbon actif Issu de la ferula communis(2020) Messabih, S.M.; Benrachedi, K.; Makhlouf, M.; Belaid, K.D.; Bouchher, Omar; Louhab, K.La présente étude est consacrée à la préparation d’un charbon actif en poudre à partir des tiges broyées de la Ferula communis récoltées dans les coteaux de la wilaya de Tipaza au nord de l’Algérie. La matière végétale a été imprégnée à l’acide phosphorique (H 3 PO 4 ), puis carbonisée à 550°C dans un four à moufle. Les résultats obtenus par caractérisation du matériau adsorbant ont montré une importante porosité et une surface spécifique de 1377 m 2 /g. Les applications de l’adsorption du colorant rouge neutre sur le charbon actif, dans un milieu aqueux, ont révélé une capacité d’élimination de l’adsorbat allant jusqu’à 666 mg/g. L’étude thermodynamique a montré que le processus de l’adsorption est spontané et endothermiqueItem Preparation and characterization study of an olive pomace - polyaniline composite conductor in the recovery of heavy metals by electrosorption and adsorption(Aljest, 2018) Babakhouya, Naouel; Abdouni, M.; Louhab, K.In this work, we have prepared a new composite material based on olive pomace (OP) and polyaniline (PANI) by the in situ-polymerization chemical method, demonstrated the ability of our material to conduct current through electrical conductivity tests.We used the spectral analysis techniques to characterize the material as well as Laser Particle Size and scanning electron microscopy to show that the PANI was successfully attached to OP.We have applied our new material in the recovery of Hexavalent Chromium by carrying out electrosorption tests at a positive potential imposed. We compared the recovery with chemical adsorption under the same conditionsItem Elimination of copper (II) in aqueous solution by adsorption on a pillared clay with polycations of aluminum and iron(International Congress of Chemistry and Environment, 2015) Cherifi-Naci, Halima; Louhab, K.; Aksas, HammoucheItem Thermodynamic of chromium sorption on biomass fungi from aqueous solution(2006) Louhab, K.; Addad, J.; Barr, S.; Goma, B.The thermodynamics of chromium ions sorption from aqueous solution on biomass fungi have been investigated. The experimental data was analysed by Langmiur and Scatchard isotherms. The equilibrium sorption capacity of chromium ions was determined from Langmiur and Scatchard equation at different temperature. Bad correlation coefficients were obtained for the Langmiur adsorption equilibrium constant. Various thermodynamics parameters, Δ H°ads, Δ S°ads and equilibrium constant values were computed at different temperature. The results show that the sorption of the chromium ions on biomass fungi is spontaneous and exothermic nature process, the thermodynamics parameters are dependent of the temperature and the equilibrium sorption capacityItem Effect of calcium competition on chromium adsorption by fungi biomass(2006) Louhab, K.; Sahmoune, Mohamed Nasser; Addad, J.; Bar, S.The kinetics and thermodynamic of adsorption of a mono-solute of chromium ions and of a bi-solute of chromium and calcium ions by fungi biomass (Streptomycine rimosus) was investigated in a batch system. The experimental data were analyzed based by Langmuir isotherm and a Pseudo second order mechanism, in the both the mono-and bi-solute adsorption systems, in order to predict the rate constant of adsorption, the equilibrium capacity. The results indicate that the adsorption mechanism is described by Langmuir isotherm and a Pseudo-second-order. The equilibrium adsorption capacity and the equilibrium rate constant increased with an increase in the initial chromium concentration in both mono-and bi-solute adsorption systems. The adsorption capacity of chromium decreased with an increase in calcium concentrationItem Adsorption of chromium Ions from aqueous solution using mixed sorbents prepared from olive stone and date pit(Ebscohost, 2012) Aksas, Hammouche; Babakhouya, Naouel; Babaci, Hakima; Feggas, R.; Louhab, K.The aim of this study is to remove chromium ions from aqueous solutions by adsorption. Mixed sorbent prepared from olive stone and date pit, an agricultural solid by-product was used as adsorbent. The adsorption experiments of Cr onto the mixture of olive stone and date pit were conducted at different parameters such as, per cent of olive stone and date pit in the mixture, temperature, initial solution pH and initial chromium concentration. Adsorption isotherms were obtained at different per cent of olive stone and date pit in the mixture. This adsorption data was fitted with the Langmuir, Freundlich and Temkin isotherms. In addition, the thermodynamic parameters, standard free energy (ΔG°), standartd enthalpy (ΔH°) and standard entropy (ΔS°) of the adsorption process were calculated. The results show that the mixture sorbent from olive stone and date pit is an alternative low-cost adsorbent for removing chromium ions
