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Item Application of Sodium Methyl Ester Sulfonate Anionic Surfactants as Corrosion Inhibitors for Carbon Steel in Oilfield Injection Water(Springer Nature, 2024) Asselah, Amel; M’Yassa, Affif Chaouche; Tazerouti, AmelAbstract: In this study, the anticorrosive properties of a series of sodium methyl ester sulfonate anionic surfactants on a carbon steel were estimated for an oilfield injection water collected from a well of Hassi R’Mel region—Algeria, known as Baremian water, and are compared to those of sodium dodecyl sulfate. This class of surfactants was synthesized from fatty acids by a photochemical process and present good physico-chemical properties and good biodegradability. The inhibition performance was evaluated by weight loss and electrochemical techniques: linear polarization resistance and electrochemical impedance spectroscopy. The results showed that these surfactants are good inhibitors; the inhibition efficiency increases with increasing concentration surfactants. In addition, the increase of chain length surfactants leads to the best inhibition efficiency for sodium sulfo palmityl methyl ester surfactant with 95.27, 98.20, and 95% via weight loss, linear polarization resistance and electrochemical impedance spectroscopy, respectively. Scanning electron microscopy–Energy dispersive X-ray allowed the visualization of a good adhesion of the protective deposit formed by the surfactants on the carbon steel surface including the elements presents on this surface as sodium and sulfur. The adsorption of these surfactants shows the maximum adherence to the Langmuir model and the values of Gibbs free energy of adsorption indicated that the inhibitor molecules are physically adsorb onto the metal surfaceItem By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study(Walter de Gruyter GmbH, 2024) Babakhouya, Naouel; Benammar, Souad; Hamitouche, Adh'ya-Eddine; Boudjemaa, Amel; Messaoud-Boureghda, Mohamed-Zine; Bachari, KhaldounAlgerian Eucalyptus Leaves (AEL), a natural biodegradable adsorbent abundantly available, was used for the removal of methylene blue (MB) dye. The AEL properties for the removal of MB were investigated under different conditions by varying the AEL amount, MB concentration, pH of the solution and the reaction temperature. Scanning electron microscopy (SEM) and infrared spectroscopy (FTIR) techniques have been used to characterize AEL biosorbent. Experimental results showed that the adsorption of MB dye at the concentration of 50 mg L-1 reached to 91 % at pH 10 with a stirring speed of 200 rpm and after 180 min of reaction time. The experimental data were analyzed using the linear forms of different kinetic models (pseudo-first order kinetic model, pseudo-second order kinetic model, and intra-particle diffusion models). The results demonstrated that the adsorption kinetics of MB was consistent with the pseudo-second order model with R 2 value of 0.9969. The isotherm models Langmuir, Freundlich, Dubinin, Elovich, Brunaut Emmet Teller and Temkin models were also investigated to describe the adsorption equilibrium. The results show that the AEL adsorption is in accordance with Temkin isotherm. The thermodynamic study revealed that the adsorption is spontaneous and exothermic. Therefore, as a cheap green adsorbent with high MB adsorption performance, AEL is expected to become one of the best candidate materials for future industrial wastewater treatment.Item Adsorption of malachite green onto walnut shells : kinetics, thermodynamic, and regeneration of the adsorbent by chemical process(Korean Fiber Society, 2023) Merrad, Samiya; Abbas, Moussa; Trari, MohamedThe textile industry produces huge amounts of wastewaters containing synthetic and toxic dyes. The aim of this study was to evaluate the adsorption of Malachite green (MG) onto Activated Carbon from Walnut Shells (ACWS) realized in a batch system. The effects of contact time, initial pH, stirring speed, particle size, temperature, adsorbent dose, and initial MG concentration on the adsorption capacity were investigated graphically for determining optimum conditions. The experimental isotherm data were analyzed by the Langmuir, Freundlich, Temkin, and Elovich models. The adsorption follows well the Langmuir equation, providing a better fit of the equilibrium adsorption data. Under optimized conditions, up to 154.56 mg/g at 25 °C and 370.37 mg/g at 45 °C were removed from the solution. The adsorption mechanism of MG onto ACWS was studied using the first-pseudo-order, second-pseudo-order, Elovich and Webber–Morris diffusion models. The adsorptions’ kinetic was found to follow rather a pseudo-second-order kinetic with a determination coefficient (R2) of 0.999. The adsorption isotherms at different temperatures have been used for the determination of thermodynamic parameters, i.e., the free energy ΔGo (0.802 to − 2.123 kJ/mol), positive enthalpy change ΔHo(18.547 kJ/mol), entropy (ΔSo = 0.064 kJ/molK), and activation energy (Ea = 14.813 kJ/mol). The negative ΔGo and positive ΔHo values indicate that the overall MG adsorption is spontaneous and endothermicItem Oxygen diffusion and migration in clean and defective uranium nitride UN (0 0 1) surfaces(Elsevier, 2018) Zergoug, T.; Abaidia, Seddik-El-Hak; Nedjar, A.This study focuses on the diffusion of atomic and molecular oxygen through the uranium mono-nitride UN (0 0 1) surface. The adsorption of oxygen at the most favorable sites has been checked on different surface states namely: clean surface and surfaces containing defects such as inclusion atoms. Inclusions atoms are positioned at a uranium U atom vacancy or at a nitrogen N atom vacancy location of the UN (0 0 1) surface. Neptunium, plutonium, protactinium, silver and neodymium which are the most probable nuclear reactions (n, U) products have been selected as U atom substitute. Some light elements such as carbon, chromium and silicon were used to replace an N atom. The first principle calculation, based on Density Functional Theory (DFT) was used, taking into account the Generalized Gradient Approximation (GGA) and the Projector-Augmented Wave (PAW) to describe the exchange-correlation functional. The purpose of this work is to verify the oxygen adsorption energy variations performed across all the studied surfaces. The most favorable sites of UN (0 0 1) clean and defective surfaces to oxygen O atom diffusion were preliminary identified. In the second step, atomic dynamical Potential Energy Surface (PES) was used to study the interaction between O atom and UN (0 0 1) surfaces at these sites. Finally, Nudged Elastic Band (NEB) method was used in order to investigate the migration of O atom through the UN (0 0 1) surfaces. The results show that at the bridge site, the adsorption and incorporation energies of oxygen atom on and in the UN (0 0 1) surfaces respectively, do not substantially vary with the type and position of the studied impurities. But, at the N vacancy site, the adsorption energy of the O atom decreases practically when UN (0 0 1) surfaces contain inclusion atoms compared to the clean surface case. Furthermore, the NEB calculations show discrepancies for the Minimum Energy Path (MEP) during the migration of the O atom at the bridge site through the studied UN (0 0 1) surfaces and depending on the type and position of the added impurities. Among the studied MEPs, protactinium is found to be the most suitable barrier to the diffusion of oxygen through the UN surface as an inclusion on UN (0 0 1)Item Removal of toxic methyl green (Mg) in aqueous solutions by apricot stone activated carbon – equilibrium and isotherms modeling(Taylor & Francis, 2018) Abbas, Moussa; Aksil, Tounsia; Trari, MohamedApricot stone activated carbon (ASAC), was powdered, activated and to be used as effective adsor-bent to remove the dyes from aqueous solutions through batch experiments under operational factors namely, pH, contact time, adsorbent dose, initial dyes concentration and temperature. The physico-chemical, morphological and structural properties of the adsorbents were characterized by scan-ning electron microscope (SEM) and X-ray diffraction (XRD) instruments. Different kinetic modelsindicated that the adsorption is well described by the pseudo-second order model. The isotherms of methyl green (MG) adsorption on ASAC were obtained and correlated with various models. The smaller RMSE values for the Langmuir and Dubinin-Radushkevic models indicated the best fitting; the mono layer adsorption capacity of MG was found to be 148.478 mg g–1 at 21°C and 88.11 mg g–1 at 46°C at pH 10. The thermodynamic functions showed spontaneous and endothermic MG adsorption. In conclusion, the adsorbent prepared from apricot stone (ASAC) was found to very effective and suitable adsorbent for reactive dyes removal from aquatic environment, due to its simple and cheap preparation, easy availability and good adsorption capacity.Item Adsorption and dissociation of H2S on the anatase TiO2 (100) surface: DFT + U study(Iop science, 2018) Nehaoua, N.; Belkada, R.; Tala-Ighil, RazikaThis paper discusses the adsorption and dissociation of the hydrogen sulfide (H2S) molecule on the titanium dioxide surface. They were studied by density function theory (DFT). The GGA + U approach was used to analyze the adsorption behavior of the H2S molecule on the TiO2 anatase (100) surface. The results presented include adsorption energies, structural and electronic properties, charge transfer and work function. Different adsorption configurations are considered with coordination of H2S at the surface (Ti5c, (Ti5c)2, O2c and O3c sites). The calculated adsorption energies are -0.31, -0.28, -1.14 and -5.66 eV. The most favorable adsorption sites lead to the dissociation of H2S into HS and H, where the S atom of HS binds to Ti5c or O2c atoms, leaving a dissociated H atom bonded to another O2c site. Analysis of Bader's charges reveals a significant charge transfer between the molecule and the surface of the TiO2 anatase. The adsorption process reduces the work function and bandgap of the system, which improves the photocatalytic properties of TiO2Item Adsorption of the Coomassie Brilliant Blue (BBC) onto apricot stone activated carbon : kinetic and thermodynamic study(Elsevier, 2014) Kaddour, Samia; Abbas, Moussa; Aksil, Tounsia; Cherfi, AbdelhamidItem Adsorption of chromium Ions from aqueous solution using mixed sorbents prepared from olive stone and date pit(Ebscohost, 2012) Aksas, Hammouche; Babakhouya, Naouel; Babaci, Hakima; Feggas, R.; Louhab, K.The aim of this study is to remove chromium ions from aqueous solutions by adsorption. Mixed sorbent prepared from olive stone and date pit, an agricultural solid by-product was used as adsorbent. The adsorption experiments of Cr onto the mixture of olive stone and date pit were conducted at different parameters such as, per cent of olive stone and date pit in the mixture, temperature, initial solution pH and initial chromium concentration. Adsorption isotherms were obtained at different per cent of olive stone and date pit in the mixture. This adsorption data was fitted with the Langmuir, Freundlich and Temkin isotherms. In addition, the thermodynamic parameters, standard free energy (ΔG°), standartd enthalpy (ΔH°) and standard entropy (ΔS°) of the adsorption process were calculated. The results show that the mixture sorbent from olive stone and date pit is an alternative low-cost adsorbent for removing chromium ions