Publications Internationales
Permanent URI for this collectionhttps://dspace.univ-boumerdes.dz/handle/123456789/13
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Item Cyanide removal from aqueous solution by oxidation with hydrogen peroxide in the presence of activated alumina-supported copper catalyst(Global NEST, 2024) Halet, Farid; Chergui, Salima; Hamdache, Farida; Boutrif, Abderrahmane; Chergui, Abdelmalek; Ould-Dris, Aissa; Boudriche, Lylia; Guénin, Erwan; Nadjemi, Boubekeur; Yeddou, Ahmed RedaCyanide compounds are widely used in some electroplating, chemical, and metallurgical industries. They are often found in their liquid discharges. This work highlights the performance of an activated alumina-supported copper catalyst in the removal of cyanide by oxidation with hydrogen peroxide in aqueous solution. The influence of catalyst dose, initial molar ratio of hydrogen peroxide/cyanides, temperature, and catalyst reuse was studied. The activated alumina-supported copper significantly enhanced the reaction rate showing a good catalytic activity. The efficiency of cyanide elimination was increased after 30 minutes of oxidation from 48% to 98% by increasing the catalyst dose from 1 to 10 g/L. Rising the temperature from 30°C to 40°C promoted cyanide removal. The catalyst can be recycled four times and show good stability. The kinetics of cyanide oxidation was revealed to be pseudo-first-order regarding cyanides. The rate constants as well as the activation energy were determined.Item Removal of cyanide in aqueous solution by oxidation with hydrogen peroxide in presence of copper-impregnated activated carbon(Elsevier, 2011) Yeddou, Ahmed Reda; Chergui, Salima; Chergui, Abdelmalek; Halet, Farid; Amaouche, Hamza; Nadjemi, Boubekeur; Ould-Dris, Aïssa; Belkouch, Jamal
