Publications Internationales

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    A review of emulsion flows, their characterization and their modeling in pumps
    (Institution of Chemical Engineers, 2024) Achour, Lila; Specklin, Mathieu; Asuaje, Miguel; Kouidri, Smaine; Belaidi, Idir
    In the engineering field, emulsions and liquid–liquid two-phase flows within centrifugal pumps are generally unwanted as emulsions will have negative effects on pump operation. Besides, emulsions are usually formed when the oil and water phases are brought together in a process called emulsification, which is enhanced by high shear rates. This topic has been extensively researched over the past decades, with sophisticated theories regarding the phenomena involved in emulsions formation and characterization in pumps. Besides, given the complexity of the physics governing emulsions, studies on their modeling within pumps, based on empirical correlations or computational fluid dynamics models, are insufficient and remain limited. This review aims to provide a complete overview of investigations on liquid–liquid flow in centrifugal pumps. Characteristics of these mixtures, such as stability, phase inversion, droplet size distribution and rheological behavior, are discussed. Current approaches and techniques for analyzing pump performance handling emulsion and two-phase liquid–liquid flow are reviewed thoroughly. The limitations of the existing models are studied, and potential future developments are proposed.
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    A novel spherical hybrid material based on the combination of humic acid/alginate/Algerian Zeen Oak sawdust for removing chromium (VI) from wastewater
    (Elsevier, 2023) Sadoun, Louiza; Benmounah, Abdelbaki; Ait-Ramdane-Terbouche, Chafia; Seffah, Karima; Terbouche, Achour
    A novel spherical hybrid material designed from the combination of humic acid (HA), sodium alginate (Al) and sawdust derived from Algerian Zeen Oak Waste (OS) has been prepared. After optimization of HA/Al/OS mass ratio, the structure of the synthesized hybrid spheres was established using various characterization techniques notably ATR, SEM-EDX, XRD, BET and the point of zero charge (pHpzc). Adsorption tests using this compound were applied to remove chromium(Cr (VI)) from aqueous solutions. The influence of the different parameters such as contact time, pH, temperature, initial metal concentration, and mass of the material were studied. The obtained results revealed that the mass of HA had a significant influence on the formation of the spheres. By varying the ratio of HA/Al/OS (1/16/16 (S1), 1/5/5 (S2), 1/3/3 (S3) and 1/2/2 (S4)), the humic acid allowed a good coating of the hybrid material. The ratio 1/5/5 (S2) was retained for the adsorption study. The efficiency of this material was subsequently tested for the removal of Cr (VI) from aqueous solutions. Optimizing the different experimental parameters allowed to obtain a removal efficiency of over 90 % for an initial Cr (VI) concentration of 60 mg L−1, at pH = 2 and temperature of 353.15 K, using 0.1 g of material. The kinetic study showed that the process of elimination of Cr (VI) followed the pseudo-second order model and well fitted with the Freundlich adsorption isotherm model with R2 value of 0.99 and a low value of χ2 (2.88). A maximum adsorption capacity of 50.328 mg.g−1 was determined by the Langmuir isotherm model. The hybrid spheres showed good regeneration efficiency even after four adsorption-desorption cycles. The thermodynamic study (ΔS = 0.091 kJ mol−1 K−1, ΔH = 24.427 kJ mol−1 and ΔG° = −2.883 kJ mol−1 at 298.15 K) revealed that the adsorption process was spontaneous, favorable and endothermic with a physisorption phenomenon. Finally, the adsorbent was successfully applied to real wastewater contaminated with chromium. This application has proved high removal efficiency of Cr (VI) and a yield of 94.31 % was obtained at 40 °C.
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    Application of Fourier Transform Infrared (FT-IR) Spectroscopy to the Study of the Modification of Epoxidized Sunflower Oil by Acrylation
    (Sage journals, 2012) Irinislimane, Ratiba; Belhaneche-Bensemra, Naima
    Commercial sunflower oil was epoxidized at the laboratory-scale. The epoxidized sunflower oil (ESFO) was modified following the acrylation reaction. Modification was carried out simultaneously using acrylic acid (AA) and triethylamine (TEA). To optimize the reaction conditions, the effects of four temperatures (40, 60, 80, and 100 °C), the ESFO:AA (100:100) ratio, and 0.2% TEA were investigated. The rate of conversion was analyzed with both FT-IR and titration of the oxirane ring. After that, the temperature with the highest conversion was selected and used throughout for all modification reactions. Then, four ratios (100:100, 100:90, 100:80, and 100:75) of ESFO:AA were analyzed at four different concentrations of TEA (0.2, 0.3, 0.4, and 0.5%) to determine the best estimate for both the ESFO:AA ratio and the catalyst concentration. Conversion rate was analyzed using FT-IR spectroscopy by measuring the concentrations of ester, carbonyl, and alcohol groups. Moreover, oxirane***ring concentration was estimated using the titration method (with gentian violet as indicator) and FT-IR spectroscopy (epoxy ring absorptions at 1270 cm−1 and 877 cm−1). Based on conversion yield, the optimum ESFO:AA ratio corresponds to 100:80; the best temperature reaction was at 60 °C, and the best TEA concentration was 0.2%. The critical amounts of reactants needed to reach maximum conversion were established. The final acid value of the acrylated ESFO after washing (pH = 7) was 2.1 mg potassium hydroxide (KOH) g−1. All results show that FT-IR spectroscopy is a simple, low-cost, rapid method for investigating the kinetics of a reaction
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    Modeling of porosity by geostatistical methods
    (Springer, 2019) Ketteb, Rachid; Djeddi,Mabrouk; Kiche,Yacine
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    Production and characterization of particleboards from cork-rich Quercus cerris bark
    (Springer, 2017) Lakreb, Nadia; As, Nusret; Gorgun, Volkan; Sen, Umut; Gomes, M. Glória; Pereira, Helena
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    Production and characterization of particleboards from cork-rich Quercus cerris bark
    (Springer, 2017) Lakreb, Nadia; Nusret, As; Volkan, Gorgun; Umut, Sen; M. Glória, Gomes; Helena, Pereira