Mass-transfer processes in the adsorption of crystal violet by activated carbon derived from pomegranate peels: Kinetics and thermodynamic studies

Abstract

This study investigates the potential use of activated carbon, prepared from pomegranate peels, as an adsorbent activated using H3PO4 and its ability to remove crystal violet from an aqueous solution. The adsorbent was characterized by the Brunauer–Emmett–Teller method (specific surface area: 51.0674 m2 g−1) and point of zero charge (pHPZC = 5.2). However, some examined factors were found to have significant impacts on the adsorption capacity of activated carbon derived from pomegranate peels such as the initial dye concentration (5–15 mg L−1), solution pH (2–14), adsorbent dose (1–8 g L−1), agitation speed (100–700 r/min), and temperature (298–338 K). The best adsorption capacity was found at pH 11 with an adsorbent dose of 1 g L−1, an agitation speed at 400 r/min, and a contact time of 45 min. The adsorption mechanism of crystal violet onto activated carbon derived from pomegranate peels was studied using the pseudo-first-order, pseudo-second-order, Elovich, and Webber–Morris diffusion models. The adsorption kinetics were found to rather follow a pseudo-second order kinetic model with a determination coefficient (R2) of 0.999. The equilibrium adsorption data for crystal violet adsorbed onto activated carbon derived from pomegranate peels were analyzed by the Langmuir, Freundlich, Elovich, and Temkin models. The results indicate that the Langmuir model provides the best correlation with qmax capacities of 23.26 and 76.92 mg g−1 at 27°C and 32°C, respectively. The adsorption isotherms at different temperatures have been used for the determination of thermodynamic parameters like the free energy, enthalpy, and entropy to predict the nature of adsorption process. The negative values ΔG0 (−5.221 to −1.571 kJ mol−1) and ΔH0 (−86.141 kJ mol−1) indicate that the overall adsorption is spontaneous and exothermic with a physisorption process. The adsorbent derived from pomegranate peels was found to be very effective and suitable for the removal of reactive dyes from aqueous solutions, due to its availability, low-cost preparation, and good adsorption capacity